Its actually near-useless for a mage.
Flame dart is better all the time. In fact, two flame darts are ALWAYS better than shadowbolt + anything for single target. Keep in mind that with high mastery, you will not get much deviation when casting your spells. My flamedarts hit for 250+ damage and up to 280 or 290 at high level. My shadowbolt is around half or less.
The only use for it, is against magic immune creatures.
On the LH board you'll notice the many recommendations to make something other flame-dart useful as there no reason to cast any other spell in combat besides perhaps a certain aoe. All other single target damage have terrible damage and terrilbe damage to mana ratios.