In the research window, there are several options on the left hand sidebar: Military Civilian, Fleet Logistics, and Artifacts. Fleet logistics has buttons that will allow you to research higher fleet capacity and slots for additional capital ships.
Be careful, though. Once you start increasing your fleet capacity, you start incurring increasing maintenance costs for your fleet. At the beginning, you don't incur maintenance at all. At the first level of increased fleet capacity, you lost 9% of all income (credits, crystal, and metal) for maintenance. So don't upgrade fleet capacity too quickly. Make sure you're actually going to use those slots you're about to pay for.